In order to exclude the effect of the background magnetoresistance and to extract the SdH oscillations, we used the negative second derivative with respect to the magnetic field of raw magnetoresistance data (-∂2 R xx /∂B 2) (see Figure 1b). As can be easily seen from Equation 1, this method does not change the position of the peak or period of the oscillations and enables to subtract the slowly changing background magnetoresistance and amplifies the short-period

oscillations [18, 19] as depicted in Figure 1b. The thermal damping of the SdH oscillations at a fixed magnetic field is determined by temperature, magnetic field, and effective mass using Equations 1 www.selleckchem.com/products/CP-673451.html to 5 as follows [19–22]: (6) where A(T, B n ) and A(T 0, B n ) are the amplitudes of the SdH oscillations at a constant magnetic field B n and at temperatures T and T 0. Using Equation 6 and SdH oscillations data at different temperatures, we derived the effective mass which we plotted in Figure 2. Figure 2 Effective mass values calculated using temperature dependence of SdH oscillations An OICR-9429 nmr enhancement of the electron effective mass compared to the N-free sample is

observed in N-containing as-grown samples, which obeys the band anti-crossing (BAC) model [4]. After thermal annealing, the electron effective mass increases, which can be attributed to the change of bandgap. It is known that incorporation of nitrogen into GaInAs lattice causes a redshift of the bandgap; on the other

hand, thermal annealing blueshifts the bandgap and the amount of blueshift increases with increasing nitrogen content selleck chemicals llc (see Table 1). The origin of the blueshift has been explained in terms of inter-diffusion of In-Ga and restructure of the nearest neighbor configuration of nitrogen [1, 9]. Table 1 PL peak energies and observed blueshift amounts at 30 K Samples PL peak energy (eV) Blueshift (meV) p-type n-type p-type n-type Ga0.68In0.32As As-grown 1.180 1.172 – - Annealed (60 s) 1.182 1.184 2 12 Annealed MG-132 price (600 s) 1.194 1.194 14 22 Ga0.682In0.32 N0.009As0.991 As-grown 1.089 1.120 – - Annealed (60 s) 1.118 1.129 29 9 Annealed (600 s) 1.146 1.137 57 17 Ga0.68In0.32 N0.012As0.988 As-grown 1.033 1.076 – - Annealed (60 s) 1.065 1.088 32 12 Annealed (600 s) 1.103 1.096 70 20 As a result of blueshift of the bandgap, conduction band states approaches localized N level, giving rise a stronger interaction; therefore, electron effective mass increases compared to the values in as-grown N-containing samples. In N-free sample, indium atoms diffuse out from the QW, leading to a decrease in In content and weaker confinement due to the reduction of the conduction band offset as a result of blueshifted bandgap. An enhancement in electron effective mass in compressively strained GaInAs layer with decreasing In content and weaker confinement was also observed by Meyer et al. [23], which is consistent with our result.